June 2022 Issue Table of Contents
International Mineralogical Association
The International Mineralogical Association (IMA) was officially launched at its first general meeting in Madrid, in April of 1958. Electronmicroprobe analysis had then just been developed by the French physicist Raimond Castaing, and the first microbeam analyses of geological samples (less than 1 μg in weight!) were about to be pub lished by him in collaboration with the Swedish mineralogist Kurt Fredriksson. Within a decade, further experiments by Castaing and his students would pave the way for secondaryion massspectrometry and electron energy loss spectroscopy, which enabled mineral analysis at the nanoscale. Significantly, these discoveries made in university labs also gave a powerful impetus to the development of a wide range of microbeam instruments. The emergence of synchrotron facilities in the 1970s and the harnessing of laser radiation for quantitative analysis, imaging, and spectroscopy in the 1980s opened new horizons for mineral scientists—particularly, in the areas of poorly crystallized and amorphous materials, phase transitions, extreme environments, and traceelement and isotope measurements—and stimulated inter disciplinary and crossfield research, which firmed up the position of our science in the study of rocks, the Earth’s interior, geochemical processes, and the biosphere. Space exploration pushed the frontiers of this research first to our celestial companion and, in the past 15 years, to asteroids and comets. Last but not least, the rapid spread of computer networks and supercomputers in the 1990s to early 2000s helped revolutionize our understanding of minerals in the context of Earth’s history and planetary evolution and ushered in the new era of mineral informatics.
Looking at this brief retrospect, one could argue that the last 60 years have been the Golden Age of Mineral Sciences. Indeed, in 1958, the 12 premier mineralogical journals cumulatively published fewer than 400 research papers in English, Russian, German, French, Italian, and Japanese. By comparison, ~600 articles were published in 2021 just on zircon, according to the Web of Science! Today, the Scimago Journal Rank lists 70 periodicals whose titles include the word “mineral,” with their scope ranging from bone metabolism to ore processing, and their geography extending from Mexico to China. The number of known minerals has increased from some 1,150 “grandfathered” by the IMA in 1958 to an impressive 5,780 species currently listed on the website of the IMA Commission on New Minerals, Nomenclature and Classification. It truly must have been a tremendous experience working through this Golden Age of discoveries, breakthroughs, and innovation! Have we, as mineral scientists, now approached an intellectual plateau, and what does the future hold? Can our developmental milestones help the younger generation of researchers choose the right career path?
For the present Perspectives, we have asked the recipients of the IMA Medal of Excellence (www.imamineralogy.org/Medal.htm) to reflect on their personal “Golden Age” experience and share their thoughts on the past, present, and future of mineral sciences. This is the first in a series of two Perspectives columns organized by the IMA. Here we feature passages composed by Distinguished Professor Emeritus Frank C. Hawthorne (University of Manitoba, Canada) and Professor Nikolay V. Sobolev (V.S. Sobolev Institute of Geology and Mineralogy, Russia), the latter of whom sadly passed away earlier this year. This column thus marks some of Prof. Sobolev’s final written contributions to the scientific commu nity. The second part of this series will appear in Elements’ December issue (vol. 18, no. 6), featuring passages written by Rodney C. Ewing, Gordon E. Brown, Jr., both of Stanford University, USA, and Robert M. Hazen of Carnegie Institution for Science, USA. The IMA Medal was established in 2006 as a lifetime achievement award that recognizes the excellence and impact of one’s contribution to knowledge, rather than the length of one’s publication list.
Frank C. Hawthorne (IMA Medalist 2009; Distinguished Professor Emeritus, University of Manitoba, Canada)
Traditionally, mineralogy has involved the description of minerals via their properties, chemical composition, and occurrence. Minerals constitute a significant part of the Earth and rocky planets, and most Earth and planetary scientists work on some aspect of minerals and their response to changing con ditions. As a result, the justification for doing mineralogy is almost always framed in terms of how useful it is to contiguous disciplines. Mineralogists are rarely funded to look at sci
entific questions that are fundamental to mineralogy itself. Why do minerals have the chemical formulae that they do? Why do minerals have their particular bond topologies? What are the atomicscale rea sons why minerals are stable over specific ranges of pH, Eh, temperature, pressure, and activities of their various constituents? What are the rela tions between bond topology and both the enthalpy and entropy of formation? What are the environmental controls on different crystal forms and habits? What mechanistic details control the sequence of crystallization and dissolution of minerals in specific environments? These questions have tended to be ignored in the past because they are intractable to standard theoretical methods and are seen as of no imme diate practical use to other branches of science. Moreover, many min eralogists do not seem interested in such matters, perhaps because mineralogy lacks a rigorous way to consider such problems and standard theoretical methods cannot deal with the size, complexity, and disorder of most minerals: e.g., veblenite, K22Na(Fe2+5Fe3+4Mn7)Nb3Ti(Si2 O7)2(Si8O22)2O6(OH)10(H2O)3 (Cámara et al. 2013).
There has been some recent work directed toward putting mineralogy on a more rigorous basis and attempting to address some of the ques tions mentioned above. Hawthorne (2015) has provided a bondtopo logical basis for mineralogy that can address many of these problems. Quantification of the structure hierarchy hypothesis (Hawthorne 2014) and the development of specific structure hierarchies—e.g., borates, sulfates, uranyl oxysalts, tellurium oxycompounds, and silicates—have led to a much greater understanding of the factors affecting the crys tallization of hydroxyhydrated oxysalts and crystallization sequences of such minerals. Mineral evolution (Hazen et al. 2008) focuses atten tion on largescale spatial and temporal mineral parageneses from early stellar materials to surficial Earth and planetary environments. The complexity of an atomic arrangement (Krivovichev 2013) has given a quantitative measure of what was hitherto only a qualitative idea, and there is the possibility of relating complexity (Shannon entropy) to questions of mineral diversity (Christy 2018; Krivovichev et al. 2018).
Although the characterization of new minerals is a baseline activity in mineralogy, novel approaches to understanding the chemical com positions, structural arrangements, and behavior of minerals in the spatial, temporal, and thermodynamic diversity of Earth and planetary environments are critical if mineralogy is to advance beyond empirical scientific activity. Significant progress is dependent on younger min eralogists becoming involved in the recent advances mentioned above and developing new rigorous methods to further our understanding of minerals and their behavior at the most basic level.
Nikolay V. Sobolev (IMA Medalist 2013; Professor, V.S. Sobolev Institute of Geology and Mineralogy, Novosibirsk, Russia)
Diamond is an exceptional member of the min eral kingdom. It is the hardest mineral with the simplest chemical composition of pure carbon, variable physical properties, and com plicated formation conditions in the litho sphere at depths exceeding 120 km. In spite of its intensive study by mineralogists, gemolo gists, physicists, chemists, and material scien tists, producing an enormous number of pub lications annually, there are many important unknowns that will need to be addressed with future diamond research.
Diamonds occur in rare mantle xenoliths, classified as peridotites and eclogites, some of which contain diamonds in proportions close to those of rockforming minerals. Systematic studies of minerals coexisting with diamonds in such xenoliths, as well as of minerals and fluids encapsulated in diamond crystals, made it possible to develop a parage netic classification similar to the one used for crustal igneous rocks. For example, the incorporation of Na in garnets and of K in clinopyroxenes associated with diamonds in peridotitic and eclogitic xenoliths was used to distinguish mantle diamond–pyrope facies from graphite–pyrope facies lacking such features (Sobolev 1977).
The composition of kimberlite indicator minerals was used for para genetic classification purposes (e.g., garnets representing harzburgite dunite, lherzolite, and wehrlite parageneses). Further paragenetic refinement is based on the composition of minerals that coexist with diamonds in mantle xenoliths and are present as inclusions in diamonds (Fig. 1), i.e., clinopyroxenefree harzburgite and/or dunite paragenesis of lowCa, highCr pyrope garnets. These developments were of prac tical importance because the indicator mineral chemistry had widely been used in kimberlite exploration since 1969. Later on, these garnets indicating diamond potential were dubbed “G10”. Indeed, the applica tion of the newly developed “mineralogical mapping technique” has been highly successful in the exploration of the Yakutian kimberlite fields in Siberia (especially for the discovery of the Yubileynaya dia mondiferous pipe) and has contributed significantly to the discovery of the Arkhangelsk kimberlite province in NW Russia. These examples illustrate the close ties between mineralogy, geology, and mineral deposit research.
Apart from encapsulated crystals, fluid inclusions are quite typical of some diamonds. The significance of hydrocarbons and CO2 for diamond formation, first postulated 60 years ago (Sobolev 1960), has received much support in recent theoretical and experimental work simulating uppermantle conditions. Many attempts have now been made to deter mine the composition of potential fluids, which required cuttingedge analytical equipment. For example, volatile components (including hydrocarbons) in garnet from diamondiferous metamorphic rocks in the Alps have been analyzed by Raman microspectroscopy (Frezzotti 2019). The predominance of higher hydrocarbons (pentane to hexa decane) and their derivatives at low levels of methane were determined by gaschromatography massspectrometry for diamond, garnet, and olivinehosted fluid inclusions in diamondiferous peridotites of the Udachnaya mine in Yakutia (Russia), suggesting that such hydrocarbons are major species in parental mantle fluids (Sobolev et al. 2019). In the first approximation, the diamond forming medium will likely turn out to be an unusual ultra potassic carbonate chloridesilicate water hydrocarbon fluid.
Elevated K levels in clinopyroxenes, as well as the unusually high Mg content of some Mg–Ca garnets, were essential to the discovery of microdiamond inclusions in garnets and zircon from metamorphic rocks at Kokchetav, Kazakhstan (Sobolev and Shatsky 1990). Accessory zircon occurring in rocks affected by ultrahighpressure metamorphism (UHPM) is of particular significance as a perfect and unique container for minerals that are completely altered in the surrounding rock. The highpressure silica polymorph coesite was found in zircon from white schists of DoraMaira in the Western Alps, eclogitehosted gneisses of Dabie Shan (China), and in coesitediamond and coesitediopside inter growths trapped in zircon from the Kokchetav gneisses (Schertl and Sobolev 2013). This research, rooted in earlier work on diamond inclu sions, greatly advanced our understanding of UHPM in crustal rocks.
This brief account of recent progress in diamond research is just one illustration of how careful and detailed mineralogical studies of one type of mineral deposit can change the way we think about such seem ingly wellunderstood things as fluids and metamorphism. On a practical side, this academic work helps geologists identify new exploration targets and solid state scientists design and test new useful materials.
Cámara F and 5 coauthors (2013) Veblenite, K22Na(Fe2+5Fe3+4Mn7)Nb3Ti(Si2 O7)2(Si8O22)2O6(OH)10(H2O)3, a new mineral from Seal Lake, Newfoundland and Labrador: mineral description, crystal structure, and a new veblenite (Si8O22) ribbon. Mineralogical Magazine 77: 29552974, doi: 10.1180/ minmag.2013.077.7.06
Christy AG (2018) The diversity of mineral species: how many are there, why do some elements form many more than others, and how complex can they get? Australian Journal of Mineralogy 19: 2133
Frezzotti ML (2019) Diamond growth
from organic compounds in hydrous fluids deep within the Earth. Nature Communications 10: 4952, doi: 10.1038/ s4146701912984y
Hazen RM and 7 coauthors (2008) Mineral evolution. American Mineralogist 93: 16931720, doi: 10.2138/am.2008.2955
Hawthorne FC (2014) The structure hierarchy hypothesis. Mineralogical Magazine 78: 9571027, doi: 10.1180/ minmag.2014.078.4.13
Hawthorne FC (2015) Toward theo retical mineralogy: a bondtopological approach. American Mineralogist 100: 696713, doi: 10.2138/am20155114
Krivovichev SV (2013) Structural com plexity of minerals: information storage and processing in the mineral world. Mineralogical Magazine 77: 275326, doi: 10.1180/minmag.2013.077.3.05
Krivovichev SV, Krivovichev VG, Hazen RM (2018) Structural and chemical complexity of minerals: correlations and time evolution. European Journal of Mineralogy 30: 231236, doi: 10.1127/ ejm/2018/00302694
Schertl HP, Sobolev NV (2013) The Kokchetav Massif, Kazakhstan: “Type locality” of diamondbearing UHP metamorphic rocks. Journal of Asian Earth Sciences 63: 538, doi: 10.1016/j. jseas.2012.10.032
Sobolev VS (1960) Formation conditions of diamond deposits. Geologiya i Geofizika 1: 722
Sobolev NV (1977) Deepseated inclu sions in kimberlites and the problem of the composition of the upper mantle. American Geophysical Union, 279 pp
Sobolev NV, Shatsky VS (1990) Diamond inclusions in garnets from metamorphic rocks: a new environment for diamond formation. Nature 343: 742746, doi: 10.1038/343742a0
Sobolev NV, Tomilenko AA, Bul’bak TA, Logvinova AM (2019) Composition of hydrocarbons in diamonds, garnet, and olivine from diamondiferous peridotites from the Udachnaya pipe in Yakutia, Russia. Engineering 5: 471478, doi: 10.1016/j.eng.2019.03.002
Sobolev NV, Seryotkin YV, Logvinova AM, Pavlushin AD, Ugap’eva SS (2020) Crystallographic orientation and geo chemical features of mineral inclusions in diamonds. Russian Geology and Geophysics 61: 634649, doi: 10.15372/ RGG2020144