Author name: Colleen M. Hansel

Cryptic Cross-Linkages Among Biogeochemical Cycles: Novel Insights from Reactive Intermediates

The biogeochemical cycling of major and minor elements in the ocean has direct bearing on the health of the planet and its inhabitants. Reactive intermediates, of both chemical and biological origin, are emerging as important players in these biogeochemical cycles. Due to their rapid production and consumption, these reactive intermediates are short-lived and typically in low concentration. Involvement of these “invisible” species in biogeochemistry may therefore be hidden, or cryptic, with no obvious lingering chemical signature. Here, we highlight reactive intermediates of the oxygen, manganese, and sulfur cycles and how these intermediates are involved in cryptic cross-linkages between marine biogeochemical cycles of global importance.

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Biogenic Uraninite Nanoparticles and Their Importance for Uranium Remediation

Biogenic uraninite is of interest to geoscientists for its importance to bioremediation strategies, remarkably small particle size, and biological origin. Recent studies have begun to illuminate the chemical/structural complexities of this important natural nanomaterial. Intriguingly, in spite of its incredibly diminutive size, the molecular-scale structure, energetics, and surfacearea-normalized dissolution rates of hydrated biogenic uraninite appear to be similar to those of coarser-particle, abiotic, stoichiometric UO2. These findings have important implications for the role of size as a moderator of nanoparticle aqueous reactivity and for the bioremediation of subsurface U (VI) contamination.

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