Author name: Glenn A. Waychunas

Activators in Minerals and the Role of Electronic Defects

Luminescence in minerals is created by ions, groups of ions, or electronic defects that can absorb energy and emit it as visible light. These units are commonly referred to as “centers” or “activators.” They can be impurities in the mineral or intrinsic constituents. In some cases, separate ions (so-called “sensitizers”) act to aid the luminescence process by preferentially absorbing energy and sending it to the emitting unit. In other cases, ions or electronic defects can slow the emission process by trapping excited electrons. Ions preventing emission from other luminescence centers are called “quenchers.” Some impurities can potentially create almost any luminescent color, while others are known for particular colored emission. Luminescence may exhibit strong zonation in crystals due to selective uptake of the activating ions.

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Structure, Chemistry, and Properties of Mineral Nanoparticles

Nanoparticle properties can show marked departures from their bulk analog materials, including large differences in chemical reactivity, molecular and electronic structure, and mechanical behavior. The greatest changes are expected at the smallest sizes, e.g. 10 nanometers and less, where surface effects are likely to dominate bonding, shape, and energy considerations. The precise chemistry at nanoparticle interfaces can have a profound effect on structure, phase transformations, strain, and reactivity. Certain phases may exist only as nanoparticles, requiring transformations in chemistry, stoichiometry, and structure with evolution to larger sizes. In general, mineral nanoparticles have been little studied.

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