Author name: Jed L. Mosenfelder

Hydrogen in the Deep Earth

Hydrogen is one of the most difficult elements to characterize in geological materials. Even at trace levels, hydrogen has a major impact on the properties of minerals, silicate melts, and fluids, and thus on the physical state of the mantle and crust. The investigation of H-bearing species in deep minerals, melts, and fluids is challenging because these phases can be strongly modified during transport to Earth’s surface. Furthermore, interpretation of experimental studies can be clouded by kinetic inhibitions and other artifacts. Nevertheless, recent improvements in analytical, experimental, and modeling methodologies have enabled advances in our understanding of how hydrogen is incorporated in the deep Earth, which is essential for constraining hydrogen cycling and storage through geologic time.

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Experimental and Observational Constraints on Halogen Behavior at Depth

Halogens are volatile elements present in trace amounts in the Earth’s crust, mantle, and core. They show volatile behavior and tend to be incompatible except for fluorine, which makes them key tracers of fluid-mediated and/or melt-mediated chemical transport processes. Even small quantities of halogens can profoundly affect many physicochemical processes such as melt viscosity, the temperature stability of mineral phases, the behavior of trace elements in aqueous fluids, or the composition of the atmosphere through magma degassing. Experiments allow us to simulate deep-Earth conditions. A comparison of experimental results with natural rocks helps us to unravel the role and behavior of halogens in the Earth’s interior.

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