Author name: Horst R. Marschall

Tourmaline Isotopes: No Element Left Behind

Tourmaline typically forms where crustal rocks interact with migrating hydrous fluids or silicate melts, and its isotopic composition provides a reliable record of the isotopic composition of the fluids and melts from which it crystallized. Minerals of the tourmaline supergroup are exceptional in their physical robustness and chemical variability, and they allow us to extract a uniquely broad range of isotopic information from a single mineral. The chemical variability of tourmaline confronts us with the difficulty of deciphering an extremely complex mineral system, but it also presents us with a geochemical recorder of half the periodic table, a breadth of representation that is unparalleled among minerals. Plate tectonic–scale geochemical cycles, local and regional fluid–rock interactions, magmatic–hydrothermal systems, ore-forming processes, and ages of tourmaline formation have all been reconstructed using this unique isotopic broadband recorder.

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High-Temperature Processes: Is it Time for Lithium Isotopes?

The field of high-temperature Li isotope geochemistry has been rattled by major paradigm changes. The idea that Li isotopes could be used to trace the sources of fluids, rocks, and magmas had to be largely abandoned, because Li diffusion causes its isotopes to fractionate at metamorphic and magmatic temperatures. However, diffusive fractionation of Li isotopes can be used to determine timescales of geologic processes using arrested diffusion profiles. High diffusivity and strong kinetic isotope fractionation favors Li isotopes as a tool to constrain the durations of fast processes in the crust and mantle, where other geochronometers fall short. Time may be the parameter that high-temperature Li isotope studies will be able to shed much light on.

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