Author name: Martin Reich

Nitrate Deposits of the Atacama Desert: A Marker of Long-Term Hyperaridity

The nitrate deposits of the Atacama Desert are unique when one considers that in most surface environments nitrate is produced or consumed by biological processes and is easily washed away by rain. Nitrate deposits have puzzled geologists since Charles Darwin’s visit to the Atacama in 1835 and several hypotheses have been proposed to explain their origin. Here, we review our current understanding of the nitrate deposits in the Atacama Desert and show that nitrate’s primary origin is predominantly atmospheric. However, its massive accumulation and preservation specifically in Atacama is due to the serendipitous convergence of climatic, tectonic and hydrologic conditions that are unique to the Central Andes.

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The Central Andes: Elements of an Extreme Land

The Central Andes and the Atacama Desert represent a unique geological, climatic, and magmatic setting on our planet. It is the only place on Earth where subduction of an oceanic plate below an active continental margin has led to an extensive mountain chain and an orogenic plateau that is second in size only to the Tibetan Plateau, which resulted from continental collision. In this article, we introduce the history of the Central Andes and the evolution of its landscape. We also discuss links between tectonic forces, magmatism, and the extreme hyperarid climate of this land that, in turn, has led to rich deposits of precious ores and minerals.

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The Paleoclimatic Signatures of Supergene Metal Deposits

Supergene metal deposits host a comprehensive record of climate-driven geochemical reactions that may span the entire Cenozoic. Products of these reactions can be dated by a variety of radiogenic isotopic methods, such as 40Ar/39Ar, (U–Th)/He, U–Pb, and U-series. The frequency of mineral precipitation, determined by dating a representative number of samples of a particular mineral collected from distinct parts of the supergene ore body, refl ects times in the geological past when weathering conditions were conducive to water–rock interaction. The frequency of mineral precipitation through time permits identifying periods in the geological past when climatic conditions were most conducive to chemical weathering and supergene ore genesis.

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Geological and Economic Significance of Supergene Metal Deposits

Supergene metal deposits form when common rock types or deeply buried primary ore bodies are exposed at or near the Earth’s surface and undergo oxidation, dissolution and reconcentration of the metals. Supergene metal deposits are economically interesting because of their accessibility for extraction and increased grades. Scientifically they are attractive because of their mineralogical diversity and what they reveal about surficial history. Apart from supplying mankind’s need for metals, supergene metal deposits provide clues about our past climate and offer an unparalleled opportunity to explore the long-term corrosion behavior of natural and man-made materials and their environmental impact.

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