Thematic Articles

Sulfide Minerals in Hydrothermal Deposits

Hydrothermal ore deposits are large geochemical anomalies of sulfur and metals in the Earth’s crust that have formed at <1 to ~8 km depth. Sulfide minerals in hydrothermal deposits are the primary economic source of metals used by society, which occur as major, minor and trace elements. Sulfides also play a key role during magmatic crystallization in concentrating metals that subsequently may (or may not) be supplied to hydrothermal fluids. Precipitation of sulfides that themselves may have little economic value, like pyrite, may trigger the deposition of more valuable metals (e.g. Au) by destabilizing the metal-bearing sulfur complexes. We review why, where and how sulfide minerals in hydrothermal systems precipitate.

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Magmatic Sulfide Ore Deposits

Magmatic sulfide ore deposits are products of natural smelting: concentration of immiscible sulfide liquid (‘matte’), enriched in chalcophile elements, derived from silicate magmas (‘slags’). Sulfide ore deposits occupy a spectrum from accumulated pools of matte within small igneous intrusions or lava flows, mined primarily for Ni and Cu, to stratiform layers of weakly disseminated sulfides within large mafic–ultramafic intrusions, mined for platinum-group elements. One of the world’s most valuable deposits, the Platreef in the Bushveld Complex (South Africa) has aspects of both of these end members. Natural matte compositions vary widely between and within deposits, and these compositions are controlled largely by the relative volumes of matte and slag that interact with one another.

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Mineralogy of Sulfides

Metal sulfides are the most important group of ore minerals. Here, we review what is known about their compositions, crystal structures, phase relations and parageneses. Much less is known about their surface chemistry, their biogeochemistry, or the formation and behaviour of ‘nanoparticle’ sulfides, whether formed abiotically or biogenically.

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Volcanoes: Characteristics, Tipping Points, and those Pesky Unknown Unknowns

The geological record of volcanic eruptions suggests that scientists are some way from being able to forecast eruptions at many of the world’s volcanoes. There are three reasons for this. First, continuing geological discoveries show that our knowledge is incomplete. Second, knowledge is limited about why, how, and when volcanic unrest turns into eruptions, and over what timescales. Third, there are imbalances between the studies of past eruptions, and the geophysical techniques and observations on modern events, versus the information needed or demanded by society. Scientists do not yet know whether there are other, presently unknown, factors that are important in controlling eruptions, or if there is an inherent unknowability about some volcanic systems.

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Dynamic Magma Systems: Implications for Forecasting Volcanic Activity

Magma systems that supply volcanoes can extend throughout the crust and consist of mush (melt within a crystalline framework) together with ephemeral magma accumulations. Within a crystal-rich mush, slow processes of melt segregation and heat loss alternate with fast processes of destablisation and magma transport. Magma chambers form by two mechanisms: incremental magma intrusion into sub-solidus rocks or the segregation and rapid merging of melt-rich layers within mush regions. Three volcanic states reflect alternations of slow and fast processes: dormancy, unrest and eruption. Monitoring needs to detect processes of melt and fluid movements in the lower and middle crust during destabilisation to improve forecasting.

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Volatiles and Exsolved Vapor in Volcanic Systems

The role of volatiles in magma dynamics and eruption style is fundamental. Magmatic volatiles partition between melt, crystal, and vapor phases and, in so doing, change magma properties. This has consequences for magma buoyancy and phase equilibria. An exsolved vapor phase, which may be distributed unevenly through reservoirs, contains sulfur and metals that are either transported into the atmosphere or into ore deposits. This article reviews the controls on volatile solubility and the methods to reconstruct the volatile budget of magmas, focusing particularly on the exsolved vapor phase to explore the role of volatiles on magma dynamics and on eruption style.

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What Does a Magma Reservoir Look Like? The “Crystal’s Eye” View

Crystals within volcanic rocks contain records of the changing chemical and thermal conditions within the magma reservoirs in which they resided before eruption. Observations from these crystal records place fundamental constraints on the processes operating within the reservoirs. Data from volcanic crystals are in accord with recent conceptual models of magma reservoirs being composed dominantly of crystal mushes, with small volumes and/or small fractions of melt present. The implication is that magma reservoirs have differing modes of behavior: magmas are stored over the long term in largely crystalline, quiescent, conditions, punctuated by brief episodes of intense activity during the decades to centuries immediately prior to an eruption.

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Global Volcano Monitoring: What Does it Mean When Volcanoes Deform?

Currently, it is only possible to look inside an active volcano using indirect geophysical methods. One such method is to measure surface deformation, which results from subsurface magmatic or hydrothermal processes. Modern satellite data allows deformation to be measured at hundreds of volcanoes without relying on limited ground instrumentation. As a result, the number of known deforming volcanoes has increased from 44 in 1997 to over 220 in 2016. This article reviews the diverse ways by which volcanoes can deform, the typical rates and durations of such deformations, and the processes that drive deformation.

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Down the Crater: Where Magmas are Stored and Why They Erupt

Magmas are erupted from a wide range of depths. Olivine compositions, for example, indicate magma storage in the lower crust and upper mantle, while clinopyroxene and amphibole record middle to upper crust storage. Pre-eruptive magmas also often cool by 100–300 °C, frequently at middle–upper crust depths, indicating clogged, ephemeral volcanic pathways. These coolings imply that mafic recharge is not a sufficient cause for eruption and that crystallization-induced vapor saturation is a more proximal eruption trigger. But an improved understanding of eruption mechanisms require precise identifications of what are herein termed “ultimate”, “proximal,” and “immediate” causes of eruption.

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On the Emergence of a Proto-Metabolism and the Assembly of Early Protocells

Life as we know it is completely dependent on metal ions. Gradients of metal ions drive metabolism, metal centers often form the active sites of enzymes, and metal-ion coordination is largely responsible for protein and RNA folding. This dependence on metal ions likely reflects the environment from which cellular life emerged. However, long chain biological polymers were not present on prebiotic Earth. Therefore, the chemical reactions leading to Earth’s first cells must have made use of alternative catalysts that were later superseded by RNA and protein. Here, we discuss the similarities between free metal ions, minerals, and biological enzyme catalysts, and how cellular life could have exploited prebiotic metallocomplexes.

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