Thematic Articles

Geochemical Tracers of Extraterrestrial Matter in Sediments

Every year, tens of thousands of tons of cosmic dust accumulate at the Earth’s surface, representing a continuation of the accretion process that started 4.57 billion years ago. The unique geochemical properties of these materials, compared to the Earth’s surface, render them excellent tracers of Solar System, atmospheric, oceanographic, and geologic processes. These processes can be recovered from the records preserved in marine and terrestrial sediments, including snow and ice. We review evidence from these natural archives to illuminate temporal and spatial variations in the flux and composition of extraterrestrial material to Earth, as well as the terrestrial processes that affect the distribution of extraterrestrial tracers in sediments.

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Organic Matter in Cosmic Dust

Organics are a significant component of most cosmic dust, as revealed from actual samples of extraterrestrial dust in the Earth’s stratosphere, in Antarctic ice and snow, in near-Earth orbit, and in asteroids and comets. Cosmic dust contains a diverse population of organic materials that owe their origins to a variety of chemical processes occurring in many different environments. The presence of isotopic enrichments of D and 15N suggests that many of these organic materials have an interstellar or protosolar heritage. The study of these samples is of considerable importance because they are the best preserved materials of the early Solar System available.

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Composition of Cosmic Dust: Sources and Implications for the Early Solar System

Many cosmic dust particles have escaped the aqueous and thermal processing, the gravitational compaction, and the impact shocks that often overprint the record, in most larger samples, of how Solar System materials formed. The least-altered types of cosmic dust can, therefore, act as probes into the conditions of the solar protoplanetary disk when the first solids formed. Analyses of these “primitive” particles indicate that the protoplanetary disk was well mixed, that it contained submicron grains formed in a diversity of environments, that these grains were aerodynamically transported prior to aggregation, which was likely aided by organic grain coatings, and that some minerals that condensed directly from the disk are not found in other materials. These protoplanetary aggregates are not represented in any type of meteorite or terrestrial rock. They can only be studied from cosmic dust.

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Cosmic Dust: Finding a Needle in a Haystack

Collecting cosmic dust is a tricky business! Despite Earth’s surface being showered by thousands of tons of comic dust every year, such dust is quickly lost in a sea of terrestrial particles. Finding the tiny cosmic treasures requires collecting dust from the cleanest environments where the terrestrial particle background is low. The stratosphere can be sampled via high-flying aircraft, whereas sampling cosmic dust from polar regions and the deep sea requires techniques that concentrate the particles. Collection efforts are worth it. Cosmic dust derives from every dust-producing object in the Solar System, including ancient Solar System materials, possibly even interstellar materials, of a type not found in meteorites.

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Cosmic Dust: Building Blocks of Planets Falling from the Sky

Throughout its history, Earth has accreted microscopic dust falling from space. Decelerating from cosmic speeds at the top of the atmosphere, the smallest particles can take weeks to reach the ground, failing a rate of 1 m−2 day−1. Although usually hidden among terrestrial materials, extraterrestrial particles can be collected from select environments and positively identified by their unique properties. Unmelted cosmic dust is often composed of large numbers of smaller silicate, sulfide, and organic components—the preserved materials from the early Solar System. Cosmic dust particles are samples of comets and asteroids and they are important samples of the initial materials that were to build the solid planets.

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Garnet: From Stone to Star

Garnet often occurs as naturally multifaceted, brightly colored, transparent, single crystals. These crystals represent chemically diverse solid solutions with a remarkable range of colors, which are largely controlled by the crystal chemistry of transition elements such as Fe, Mn, Ti, Cr, and V. These same optical properties have given garnet important cultural and historical relevance as a sought-after gemstone, from biblical times to the present day.

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Garnet: A Key Phase in Nature, the Laboratory, and Technology

Silicate garnet is a key rock-forming mineral, and various synthetic nonsilicate garnets find important use in a number of technological areas. Garnet’s crystal structure provides the basis upon which many microscopic–macroscopic property relationships may be understood. Most rockforming garnets are substitutional solid solutions and, thus, mineral scientists are focusing their efforts on investigating local structural properties, lattice strain, and thermodynamic mixing properties. Nonsilicate compositions are used, or have potential use, in various scientific and industrial areas because of their magnetic, optical, lasing, and ion-conducting properties. Research on garnet is multidisciplinary and involves scientists in the materials and mineral sciences, physical and inorganic chemistry, and solid-state physics.

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Metamorphism as Garnet Sees It: The Kinetics of Nucleation and Growth, Equilibration, and Diffusional Relaxation

Garnet bears witness to the importance of kinetics during metamorphism in its microstructural features, compositional zoning, and diffusional response to thermal events. Porphyroblastic textures carry quantitative signals of protracted nucleation and sluggish intergranular diffusion, key impediments to reaction progress that may result in crystallization under conditions well removed from equilibrium. Growth zoning in garnet reveals partial chemical equilibration with matrix minerals: intergranular transport keeps pace with garnet growth for some elements but not for others, leading to variable degrees and length scales of chemical equilibration. Partial relaxation of compositional zoning by intracrystalline diffusion is a sensitive and quantitative indicator of thermal history, constraining rates and timescales of peak metamorphic heating, processes of burial and exhumation, and retrogression on cooling.

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Garnet Geochronology: Timekeeper of Tectonometamorphic Processes

Garnet’s potential as a chronometer of tectonometamorphic processes and conditions was fi rst recognized over 30 years ago. The Sm–Nd and Lu–Hf systems have since emerged as the most effective chronometers, permitting age precision of better than ±1 My, even on tiny samples such as concentric growth zones within individual crystals. New, robust analytical methods mitigate the effects of ubiquitous mineral inclusions, improving the precision and accuracy of garnet dates. Important differences between Sm– Nd and Lu–Hf with respect to partitioning, diffusivity, contaminant phases, and isotopic analysis make these two systems powerfully complementary.

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Garnet: Witness to the Evolution of Destructive Plate Boundaries

Thanks to its unique chemical and mechanical properties, garnet records evidence of rocks’ paths through the crust at tectonic plate boundaries. The compositions of garnet and coexisting mineral phases permit metamorphic pressure and temperature to be determined, while garnet’s compositional zoning allows the evolution of these parameters to be constrained. But careful study of garnet reveals far more, including the dehydration history of subducted oceanic crust, the depths reached during the earliest stages of continental collision, and the mechanisms driving heat and mass flow as orogens develop. Overall, chemical and textural characterization of garnet can be coupled with thermodynamic, thermoelastic, geochronologic, diffusion, and geodynamic models to constrain the evolution of rocks in a wide variety of settings.

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