Thematic Articles

Early Stages of Mineral Formation in Water: From Ion Pairs to Crystals

Minerals can precipitate from aqueous solutions via a fascinating variety of pathways. Classically, these pathways were thought to be initiated by a single-step nucleation mechanism. Over the past two decades, several investigations revealed that minerals can form through multi-step processes, from dissolved single ions to the final stable crystal. Depending on the mineral system under investigation and its environment, alternative mechanisms are possible, including ion-by-ion aggregation and agglomeration of clusters of ions. Intermediate species can be intriguingly variable: from ion pairs and ion clusters, to dense liquids, amorphous phases, meso- and (charged) nanocrystals. Here we provide a summarized overview of our current knowledge about processes taking place during the prenucleation stage.

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A Mineral World

Minerals are indispensable components of our daily lives, sought after for their importance in natural and industrial processes, as well as their aesthetic appeal. There have long been established theories on mineral formation mechanisms, but many questions remain unanswered, and evidence suggests that our traditional view of crystallization is too simplistic. In recent decades, there has been a renaissance in this field, with new studies shedding light on the underlying physical processes. This introductory chapter aims to provide readers with a concise overview of the intricate world of mineral crystallization and its relevance in various research fields, including biomineralization, geochemistry, and industrial applications.

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Himalayan Leucogranites: Rare-metal Resources

Himalayan leucogranites were once overlooked for rare-metal resources because they initially were thought to have formed by in-situ partial melting of underlying high-grade metamorphic rocks. However, recent findings have revealed widespread rare-metal mineralizations of Be, Nb/Ta, Li/ Rb/Cs, and W/Sn associated with leucogranites in the area, suggesting these mineralizations resulted from extensive fractionation of leucogranitic magmas during long-distance magma transport along the low-angle South Tibetan Detachment System. When combined with coeval Au-Sb-Pb/Zn mineralizations in the Himalayas of the Indian plate, and porphyry Cu-Mo mineralizations in the Gangdese of the Asian plate, a specific Himalayan-type mineralization is proposed to describe the metallogenesis related to the exhumation of the subducted Indian continent, coinciding with the uplift of the Himalayan mountains.

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Himalayan Leucogranites: A Geochemical Perspective

The geochemical characterization of Himalayan leucogranites offers important insights into both their petrogenesis and Himalayan orogenic processes. Himalayan leucogranites are characterized by strongly peraluminous compositions that are comparable to melts derived from anatexis of sedimentary rocks. Their radiogenic (Sr, Nd, and Hf) isotopic compositions point to metasediments from the Higher Himalayan Sequence of the Indian plate as the primary source rocks, with minor contributions from other lithologies. Himalayan leucogranites display considerable variability in trace element ratios (e.g., Rb/Sr, Nb/Ta, Zr/Hf, and Eu/Eu*) and significant fractionation of non-traditional stable isotopes (e.g., Mg, K, Zn, Rb, and Ba), which provide key constraints on the respective roles of source heterogeneity, crystal fractionation, magma–fluid interaction, and crustal melting in their formation.

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Himalayan Leucogranites: An Experimental Petrology Perspective

The High Himalayan leucogranites (HHL) are produced by muscovite breakdown of a metapelitic source, at temperatures below 800°C, with initial melt water contents of ~5–7 wt.%. The tourmaline-rich HHL variety is colder, possibly a fractionation product of the hotter two-mica HHL. HHL lack restites such as iron-rich garnet, which, when present, is Mn-rich, signaling fractionation processes. The low redox state of HHL mirrors that of their graphite-bearing source, yet there is evidence of a significant increase in fO2 during crystallization of some HHL. Their relationships with regional deformation call for late emplacement of the main bodies, which must have cooled at 3–4 kb to allow muscovite crystallization, which in turn imposes stringent constraints on unroofing rates of the collisional chain.

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Himalayan Leucogranites: A Minimal Role in Deformation

A popular model of Himalayan metamorphic and structural evolution argues that partial melting of deeply buried rocks triggered crustal weakening, ductile flow, orogenic collapse, and genesis of leucogranites. Here, we review the origins and evolution of partial melts and leucogranites to demonstrate that they are largely incidental to deformation. Although a pulse of orogenic collapse and leucogranite crystallization occurred at 15–25 Ma, pervasive partial melts formed as much as 20 My earlier. Thus, leucogranites date extraction and transport, not necessarily melting onset. Extensional structures and distributed extensional strain occur in many rocks that lack partial melt and leucogranites, indicating these are not prerequisite to facilitate orogenic collapse. Most mass transfer appears to occur via thrusting, even in partially molten rocks.

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Himalayan Leucogranites: Field Relationships and Tectonics

Himalayan peraluminous leucogranites were derived from in-situ melting of sillimanite + K-feldspar-bearing pelite-migmatite, and were transported via layer-parallel sill complexes and cross-cutting dykes to feed giant sills up to 5 km thick. Partially melted Himalayan middle crust was extruded southwards between two large-scale, north-dipping, synchronous ductile shear zones: the Main Central Thrust (MCT) below and the low-angle normal fault South Tibetan Detachment (STD) above. U-Th/Pb monazite dating constrains granite melting to ~25–18.5 Ma in Manaslu and ~24–13 Ma in Everest-Makalu. The Manaslu sheeted sill complex was emplaced by progressive underplating with the oldest intrusions structurally above younger intrusions. Heat was dominantly derived by internal radioactive heating from crustal thickening with little or no contribution from shear heating along the MCT or from the mantle.

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Himalayan Leucogranites: Petrogenesis and Significance

Himalayan leucogranites crop out intermittently over 2000 km along the crest of the world’s youngest and largest mountain range. They are derived from partial melting of continental crust during a classic continental collisional orogeny. Studies of these leucogranites have significantly advanced knowledge of crustal anatexis, felsic magmatic differentiation, and the tectonic evolution of the Himalayan-Tibetan orogen. This Elements thematic issue provides an overview of the petrogenesis and significance of the Himalayan leucogranites including field relations, source rocks, petrology, geochemistry, tectonics, and links to orogenesis and economic resources. It not only summarizes the state-of-the-art research on Himalayan leucogranites but also demonstrates how a multidisciplinary approach can help constrain the origins and evolution of granites, their associated mineralizations, and related geodynamic development.

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Luminescence Applications in Ore Geology, Mining, and Industry

Luminescence applications in ore geology, mining, and beneficiation include remote prospecting, ground-based exploration, and radio metric sorting. Remote prospecting for ores with a drone or helicopter- borne luminescent sensing using laser excitation and time-delayed detection is becoming commonplace. Modern ground-based exploration increasingly utilises outlining of luminescing “fugitive calcite” veinlet halos, whose characteristics can rapidly and inexpensively give information on the overall size of a mineralised system and the principal structural controls on ore fluid migration pathways. Diamonds and scheelite have been found and recovered through X-ray luminescent radiometric sorting, while laser-induced luminescence has great potential, especially for sorting diamonds lacking X-ray luminescence, fluorite, spodumene, and rare earth element (REE)–bearing minerals. The luminescence concept is expanded here to include laser-induced breakdown spectroscopy; its fusion with X-ray techniques provides simultaneous information on both the mineralogical and chemical composition of a rock.

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Analysing the Luminescence of Gems

Luminescence imaging and spectroscopy have become essential in gem testing, as most gem minerals and materials exhibit specific luminescence when properly excited. With a range of techniques introduced in gem testing laboratories in the past quarter century, such as luminescence imaging and photoluminescence (PL) emission and excitation spectroscopies, there are many applications to gem materials for establishing their identity, separating natural from synthetic gems, and detecting potential treatments. Further, these techniques often give clues towards the identity of emitting defects. Luminescence-based testing has recently gained attention even outside the gemmological laboratory as many simple luminescence-based instruments are offered to the gem and jewellery trade to separate natural from synthetic diamonds or from their imitations.

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