Thematic Articles

Apatite: A Fingerprint for Metasomatic Processes

Apatite is a superb mineral by which to investigate the nature of fluids that have passed through and altered a rock (metasomatic processes). Its ubiquity allows it to act as a reservoir for P, F, Cl, OH, CO2, and the rare earth elements. It is also a powerful thermochronometer and can be chemically altered by aqueous brines (NaCl–KCl–CaCl2–H2O), pure H2O, and aqueous fluids containing CO2, HCl, H2SO4, and/or F. Thus, apatite is the perfect tracker of metasomatic fluids, providing information on the timing and duration of metasomatism, the temperature of the fluids, and the composition of the fluids, all of which can feed back into the history of the host rock itself.

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Structurally Robust, Chemically Diverse: Apatite and Apatite Supergroup Minerals

Apatite is ubiquitous in igneous, metamorphic, and sedimentary rocks and is significant to more field of study than perhaps any other mineral. To help understand why, one needs to know apatite’s structure, composition, and crystal chemistry. Apatite has a robust hexagonal atomic framework based on two distinct metal-cation sites (M1, M2), a tetrahedral-cation site (T), and an anion column along four edges of the unit cell. These cation and anion sites can, among them, incorporate more than half of the long-lived elements in the periodic table, giving rise to the “apatite supergroup,” which contains over 40 mineral species. The structure and composition impart properties that can be technologically, medically, and geologically very useful.

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Global Continental Arc Flare-ups and Their Relation to Long-Term Greenhouse Conditions

Continents are long-term storage sites for sedimentary carbonates. Global fl are-ups in continental arc volcanism, when arc magmas intersect and interact with stored carbonates, thus have the potential for elevating the global baseline of deep Earth carbon inputs into the atmosphere, leading to long-lived greenhouse conditions. Decarbonation residues, known as skarns, are ubiquitously associated with the eroded remnants of ancient batholiths, attesting to the potential link between continental arc magmatism and enhanced global CO2 inputs to the atmosphere.

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Collisional Processes and Links to Episodic Changes in Subduction Zones

Continental collision is commonly accompanied by a sequence of several plate–mantle interactions, including accretion of buoyant features, pulses of slab rollback, slab break-off, formation of slab windows, and lithosphere delamination. Using the combined insight from seismic and dynamical modelling studies, we illustrate how these processes and their characteristic rates and timescales played an important role in shaping the Mediterranean and how they dominated the closure of the Tethyan oceans. Older collisions, such as the one that formed the Norwegian Caledonites, probably experienced similarly complex plate–mantle interaction, even though direct evidence of the associated mantle dynamics is absent.

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Quickening the Pulse: Fractal Tempos in Continental Arc Magmatism

The magmatic history of a continental arc can be characterized as punctuated equilibrium, whereby long periods of low-level activity are interrupted periodically by short bursts of high-volume magmatism (“fl are-ups”). Geochronological records, most notably from zircon, reveal episodicity in volcanism, pluton formation, and detrital sedimentation in, and associated with, arc segments and volcano-plutonic suites. Distinct tempos can be recognized at all resolvable spatial and temporal scales and are broadly fractal, with each scale reflecting the timescale of processes occurring at different levels in the arc crust. The tempos of continental arc magmatism thus reflect modulation of the mantle-power input as it is progressively filtered through the continental crust.

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Magma Production Rates for Intraoceanic Arcs

Intraoceanic volcanic arcs have long been recognized as sites where continental crust is created. Yet, despite their importance to understanding magmatic systems and the evolution of our planet, very little is known about their long-term rates of magma production and crust formation. Constraining both crustal construction and destruction processes at intraoceanic arcs allows for improved estimates of magma production. Our revised magma production rates for active intraoceanic arcs are consistent with those calculated for mid-ocean ridge segments that have slow to moderate spreading rates. This is surprising because magma production at intraoceanic arcs has traditionally been assumed to be significantly less than that at mid-ocean ridges.

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High-Volume Magmatic Events in Subduction Systems

The world’s biggest Phanerozoic magmatic arcs formed above subduction zones and comprise the products of continuous magma emplacement into the crust over periods of up to 500 My. However, the intensity of magmatic activity can vary significantly. Punctuated magmatic events lasting from 5 to 20 My can dwarf the volume of magmas generated through the remainder of an arc’s history: these high-volume events are called “fl areups” and can completely rebuild an arc’s crust. In arcs formed on continental lithosphere, fl are-ups typically correlate with regional structural events that shorten and/or thicken the crust. Geochemical and isotopic signatures show that these high magmatic addition rate events involve ~50% recycled upperplate crust and mantle lithosphere; the remaining ~50% comes from the mantle wedge.

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Arc Magmatic Tempos: Gathering the Evidence

In this issue of Elements we explore the characteristics, potential causes, and implications of episodic magmatism in arcs. A comparison of U–Pb bedrock and detrital zircon ages in arcs with independent calculations of volumetric magma addition rates (MARs) indicates that the former nicely track the episodic temporal histories of arc magmatism but not MARs. MAR estimates indicate that 100–1000 times more magmatism is added to continental arcs during fl are-ups than during lulls and result in plutonic/volcanic ratios of >30/1. Episodic arc magmatism may result from external forcing on arc systems caused by events outside the arc and/or from internal cyclic processes driven by feedback between linked tectonic and magmatic processes within the arc. Along and across arc strike, changes and asymmetries in magmatic, tectonic, and geochemical histories provide important constraints for evaluating these poorly understood driving mechanisms.

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Volatile and Isotopic Imprints of Ancient Mars

The science investigations enabled by Curiosity rover’s instruments focus on identifying and exploring the habitability of the Martian environment. Measurements of noble gases, organic and inorganic compounds, and the isotopes of light elements permit the study of the physical and chemical processes that have transformed Mars throughout its history. Samples of the atmosphere, volatiles released from soils, and rocks from the floor of Gale Crater have provided a wealth of new data and a window into conditions on ancient Mars.

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Determining Mineralogy on Mars with the CheMin X-Ray Diffractometer

The rover Curiosity is conducting X-ray diffraction experiments on the surface of Mars using the CheMin instrument. The analyses enable identification of the major and minor minerals, providing insight into the conditions under which the samples were formed or altered and, in turn, into past habitable environments on Mars. The CheMin instrument was developed over a twenty-year period, mainly through the efforts of scientists and engineers from NASA and DOE. Results from the first four experiments, at the Rocknest, John Klein, Cumberland, and Windjana sites, have been received and interpreted. The observed mineral assemblages are consistent with an environment hospitable to Earth-like life, if it existed on Mars.

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