Thematic Articles

Groundwater: A Resource in Decline

Around the world, groundwater sources are in decline due to overpumping and pollution. History informs us that as water supplies are lost so are civilizations. Such was the case with the Garamantian civilization, which thrived in the western Libya desert from 500 BCE to 400 CE, then disappeared when the groundwater ran out. Present-day mining of groundwater from large aquifers in the United States, North Africa, and China illustrates this problem. In less than a century, pressures from food production and population growth are leading to declines in supplies that appeared to many as inexhaustible. In many countries, there can be no replacement for declining water resources. Food scarcity and health epidemics, leading to societal decline, are likely outcomes as people chase dwindling water supplies.

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Hydrogeochemical Processes and Controls on Water Quality and Water Management

The chemical constituents in water determine its potability, usability for agriculture and recreation, and interactions with biological systems. Anthropogenic processes have significantly influenced the geochemistry of water in many regions. Physical, chemical, and biological processes control the chemistry and chemical evolution of water in natural and contaminated systems. Advances in our ability to quantify these processes will improve our ability to manage our water resources, help us identify potential sources of contamination, and illuminate potential solutions to water-quality problems. Particularly impressive are the applications of chemical and isotopic tracers, which can track water movement and quantify water fluxes on the surface and in the subsurface. To better address societal needs, future advances will require a holistic approach to interpreting geochemical data.

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Water and Sanitation in Developing Countries: Geochemical Aspects of Quality and Treatment

Safe drinking water and basic sanitation are key elements of the Millennium Development Goals, a United Nations initiative. The microbial quality of drinking water is inherently linked to sanitation practices because fecal pathogens are the most common source of drinking water contamination in developing countries. Filtration of water through soil and aquifer sediments can provide natural protection against pathogens, and this makes groundwater an attractive option for safe drinking water supply. Groundwater quality may, however, be compromised by the leaching of natural chemical constituents from geologic materials. Conversely, geochemical processes provide the basis both for the removal of such contaminants and for the recovery of nutrients from wastewater through physicochemical treatment.

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Water: Is There a Global Crisis?

Providing safe drinking water to the world’s 6.9 billion and growing population is one of the greatest challenges of the century. Consideration of the global water cycle, however, shows that the available renewable freshwater resources exceed the current human demand by roughly a factor of 10. Scarcity results from the uneven spatial and temporal distribution of water. Over-withdrawal of surface water and groundwater has led to depletion of water resources and environmental damage in some regions. In many developing countries, inadequate sanitation is a major cause of disease. These problems can be solved through the improved management of water infrastructure and water resources, advances in technology, and a valuation of water that reflects its importance to society. The role of Earth scientists in addressing the global water crisis is crucial. Indeed, resource monitoring, development of novel waste-water treatment technologies, and determination of the quantities of water that can be withdrawn without causing adverse effects on the environment will be essential for the efficient management of global water resources in the future.

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Recycling, Reuse and Rehabilitation of Mine Wastes

If we want to ensure a sustainable future for the human race, we must learn to prevent, minimize, reuse and recycle waste. Reuse of mine wastes allows their beneficial application, whereas recycling extracts resource ingredients or converts wastes into valuable products. Yet, today, many of the proposed reuse and recycling concepts for mine wastes are not economic. Consequently, the great majority of mine wastes are still being placed into waste storage facilities. Significant research efforts are required to develop cost-effective reuse and recycling options and to prevent the migration of contaminants from rehabilitated waste repositories in the long term.

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Mine Wastes and Human Health

Historical mining and mineral processing have been linked definitively to health problems resulting from occupational and environmental exposures to mine wastes. Modern mining and processing methods, when properly designed and implemented, prevent or greatly reduce potential environmental health impacts. However, particularly in developing countries, there are examples of health problems linked to recent mining. In other cases, recent mining has been blamed for health problems but no clear links have been found. The types and abundances of potential toxicants in mine wastes are predictably influenced by the geologic characteristics of the deposit being mined. Hence, Earth scientists can help understand, anticipate, and mitigate potential health issues associated with mining and mineral processing.

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Mine Waters: Acidic to Circumneutral

Acid mine waters, often containing toxic concentrations of Fe, Al, Cu, Zn, Cd, Pb, Ni, Co, and Cr, can be produced from the mining of coal and metallic deposits. Values of pH for acid mine waters can range from –3.5 to 5, but even circumneutral (pH ≈ 7) mine waters can have high concentrations of As, Sb, Mo, U, and F. When mine waters are discharged into streams, lakes, and the oceans, serious degradation of water quality and injury to aquatic life can ensue, especially when tailings impoundments break suddenly. The main acid-producing process is the exposure of pyrite to air and water, which promotes oxidative dissolution, a reaction catalyzed by microbes. Current and future mining should plan for the prevention and remediation of these contaminant discharges by the application of hydrogeochemical principles and available technologies, which might include remining and recycling of waste materials.

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Waste Streams of Mined Oil Sands: Characteristics and Remediation

The bitumen found in the oil sands of northern Alberta, Canada, represents a significant oil resource. This bitumen is extracted either from mined ore or by using in situ methods. The water-based extraction of mined ore creates large volumes of mineral suspensions that are stored in tailings ponds. Remediation of fine tailings has presented challenges. Several new treatment technologies promise to accelerate the remediation process and at the same time recover more water for use in the extraction process. As a world-class oil reserve, and the only commercially developed oil sand deposit, the Alberta oil sands represent an important future oil source, the magnitude of which will depend to some extent on our ability to limit environmental impacts.

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Geochemistry and Mineralogy of Solid Mine Waste: Essential Knowledge for Predicting Environmental Impact

Large volumes of waste rock and mine tailings are stored at mine sites. Predicting the environmental impact of these wastes requires an understanding of mineral–water interaction and the characterization of the solid materials at the microscopic scale. The tendency of mine wastes to produce acid or neutral drainage containing potentially toxic metals generally reflects the ratio of primary sulfide to carbonate minerals and the trace element concentrations inherited from the ore deposit, as well as any ore processing that may have created new compounds. Whether potentially toxic elements are released to surface water, groundwater, or bodily fluids (in the case of ingestion or inhalation) depends on the host mineral and the possibility of sequestration by secondary minerals.

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Mine Wastes: Past, Present, Future

Mine wastes are unwanted, currently uneconomic, solid and liquid materials found at or near mine sites. Volumetrically they are one of the world’s largest waste streams, and they often contain high concentrations of elements and compounds that can have severe effects on ecosystems and humans. Multidisciplinary research on mine wastes focuses on understanding their character, stability, impact, remediation and reuse. This research must continue if we are to understand and sustainably manage the immense quantities of historic, contemporary and future mine wastes, given the trend to exploit larger deposits of lower-grade ores.

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