Thematic Articles

Chronometry of Meteorites and the Formation of the Earth and Moon

The planets of the Solar System grew by collisions, starting with the aggregation of tiny dust particles within the solar nebula and culminating in giant collisions between large planetary bodies. These giant impacts occasionally caused the formation of satellites such as the Earth’s Moon. Our understanding of planet formation is based on information from various sources, including meteorites – leftovers from the earliest stages of planet formation – and samples from the Earth and Moon. By combining results from isotopic dating of these materials with dynamic modelling of the solar nebula and planet formation, researchers can reconstruct the accretion and early evolution of planetary bodies during the first ~100 million years of Solar System history.

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Organic Chemistry of Carbonaceous Meteorites

The early Solar System contained a wide range of abiotic organic compounds. As the Solar System evolved, these organic molecules were incorporated into planetesimals and eventually planetary bodies, such as the parent bodies of meteorites. One particular class of meteorites, the carbonaceous meteorites, contains a large variety of extraterrestrial organic compounds. These compounds represent a record of the chemical reactions and conditions in the early Solar System. Different formation mechanisms and sources (interstellar, nebular or parent body) contributed to the inventory of meteoritic organic molecules. Their subsequent delivery to the early Earth may have contributed the first prebiotic building blocks of life.

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The Asteroid–Comet Continuum: In Search of Lost Primitivity

Recent results from the Stardust comet sample-return mission have confirmed the idea that there is a continuum between primitive small bodies in the outer main asteroid belt and comets. Indeed, the mineralogy as well as the chemical and oxygen isotope compositions of the dust from comet Wild 2 are very similar to those of carbonaceous chondrites, a class of meteorites allegedly derived from primitive, dark asteroids. Comets no longer represent extremely primitive samples of the early Solar System that are radically different from dark asteroids. We enter a new era in which comets and their siblings, the dark asteroids, are seen as a collection of individual objects whose geology can be studied. The most primitive of these objects, i.e. the ones that escaped thermal metamorphism or hydrothermal alteration, can help us decipher physicochemical processes in the interstellar medium and in the protoplanetary disk from which our Solar System formed.

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Stable Isotope Cosmochemistry and the Evolution of Planetary Systems

Stable isotopes record the evolution of planetary systems, beginning with stars coalescing from molecular clouds, followed by the nucleosynthesis of elements in stars, and proceeding to the accretion and differentiation of planets. Current stable isotope measurements range in scale from isotopic mapping of the Milky Way Galaxy with spectrographs on telescopes to the analysis of stardust with ion probes

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Presolar History Recorded in Extraterrestrial Materials

Extraterrestrial samples include a rich variety of materials with different histories. Among the array of Solar System materials are tiny grains with extremely anomalous isotopic compositions—records of nucleosynthetic processes that occurred deep within their now extinct parent stars. The isotopic and mineralogical characterization of these presolar grains in the laboratory provides unprecedented insight into stellar and galactic evolution, nucleosynthesis, and dust formation and processing. The discovery of presolar grains has opened up a pivotal new dimension in the field of astrophysics. Coupled with astronomical observations and astrophysical studies, stardust analyses bring nanometer-scale detail to the history of our immense Galaxy.

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A Cosmochemical View of the Solar System

Cosmochemistry is the study of extraterrestrial materials aimed at understanding the nature of Solar System bodies, including the planets, their natural satellites, and small bodies. An important goal is to increase our understanding of the chemical origin of the Solar System and the processes by which its planets and small bodies have evolved to their present states. Research in cosmochemistry covers an enormous range of disciplines and techniques, including mineralogy, petrology, major and trace element chemistry, isotope compositions, radiometric ages, magnetism, and radiationexposure effects. These studies provide a wealth of data about the processes of stellar evolution, planetary-system formation, alteration in asteroidal and cometary interiors, and the accretion history of the Earth, including the origin of Earth’s volatile and organic materials.

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Nanoparticles for Remediation: Solving Big Problems with Little Particles

Remediation with engineered nanomaterials (ENMs) promises more effective and cheaper approaches than conventional methods due to the increased reactivity of nanoparticles and the possibility of in situ treatment. Three examples of the use of ENMs in soil remediation are nanoscale zero-valent iron for the degradation of halogenated organic compounds, nanoscale calcium peroxide for the destruction of organics (e.g. gasoline) and nanoscale metal oxides for the adsorption of metals. However, these methods are very new, and more research is needed on the mobility of ENMs in the soil and their impact on the environment.

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Bioremediation: Working with Bacteria

Soil bioremediation is a complex and costly process that aims to restore contaminated sites to environmentally sustainable conditions using microorganisms. The process relies upon the ability of microorganisms to degrade organic molecules, but it also depends on the microorganisms coming into contact with the contaminants, and the environment in the contaminated soil being conducive to the survival of the bacteria. A wide variety of techniques have been developed to ensure that these latter two constraints are overcome and to enhance contaminant biodegradation. Future developments in bioremediation are likely to lead to a reduction in both the energy used and the resulting pollutant and greenhouse gas emissions.

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Assisted Phytoextraction: Helping Plants to Help Us

Phytoextraction is a process in which plants are used to remove trace metal contaminants from soils. This approach for cleaning soils appears very attractive, but essentially it is still at the development stage. Assisted phytoextraction, also called enhanced phytoextraction, seeks to improve metal extraction rates by manipulating the growing conditions of the plants. However, major technical challenges remain to be resolved.

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Mineral-Based Amendments for Remediation

Amending soils with mineral-based materials to immobilize contaminants is both old and new. Although mineral amendments have been used for decades in agriculture, new applications with a variety of natural and reprocessed materials are emerging. By sequestering contaminants in or on solid phases and reducing their ability to partition into water or air, amendments can reduce the risk of exposure to humans or biota. A variety of mineral types are commonly used to amend contaminated soils, with different modes of molecular-scale sequestration. Regulatory, social, and economic factors also influence decisions to employ mineral amendments as a treatment technology.

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