Thematic Articles

Earth’s Outgassing and Climatic Transitions: The Slow Burn Towards Environmental “Catastrophes”?

On multimillion-year timescales, outgassing from the Earth’s interior provides the principal source of CO2 to the ocean–atmosphere system, which plays a fundamental role in shaping the Earth’s baseline climate. Fluctuations in global outgassing have been linked to icehouse–greenhouse transitions, although uncertainties surround paleo-outgassing fluxes. Here, we discuss how volcanic outgassing and the carbon cycle have evolved in concert with changes in plate tectonics and biotic evolution. We describe hypotheses of driving mechanisms for the Paleozoic icehouse–greenhouse climates and explore how climatic transitions may have influenced past biotic crises and, in particular, how variable outgassing rates established the backdrop for carbon cycle perturbations to instigate prominent mass extinction events.

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Deep Carbon and the Life Cycle of Large Igneous Provinces

Carbon is central to the formation and environmental impact of large igneous provinces (LIPs). These vast magmatic events occur over geologically short timescales and include voluminous flood basalts, along with silicic and low-volume alkaline magmas. Surface outgassing of CO2 from flood basalts may average up to 3,000 Mt per year during LIP emplacement and is subsidized by fractionating magmas deep in the crust. The large quantities of carbon mobilized in LIPs may be sourced from the convecting mantle, lithospheric mantle and crust. The relative significance of each potential carbon source is poorly known and probably varies between LIPs. Because LIPs draw on mantle reservoirs typically untapped during plate boundary magmatism, they are integral to Earth’s long-term carbon cycle.

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The Influence of Large Bolide Impacts on Earth’s Carbon Cycle

Human society’s rapid release of vast quantities of CO2 into the atmosphere is a significant planetary experiment. An obvious natural process capable of similar emissions over geologically short time spans are very large bolide impacts. When striking a carbon-rich target, bolides significantly, and potentially catastrophically, disrupt the global biogeochemical carbon cycle. Independent factors, such as sulfur-rich targets, redox state of the oceans or encountering ecosystems already close to a tipping point, dictated the magnitude of further consequences and determined which large bolide strikes shaped Earth’s evolution. On the early Earth, where carbon-rich sedimentary targets were rare, impacts may not have been purely destructive. Instead, enclosed subaqueous impact structures may have contributed to initiating Earth’s unique carbon cycle.

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On the Origin(s) and Evolution of Earth’s Carbon

The isotopic “flavor” of Earth’s major volatiles, including carbon, can be compared to the known reservoirs of volatiles in the solar system and so determine the source of Earth’s carbon. This requires knowing Earth’s bulk carbon isotope value, which is not straightforward to determine. During Earth’s differentiation, carbon was partitioned into the core, mantle, crust, and atmosphere. Therefore, although carbon is omnipresent within the Earth system, scientists have yet to determine its distribution and relative abundances. This article addresses what we know of the processes involved in the formation of Earth’s carbon reservoirs, and, by deduction, what we know about the possible origins of Earth’s carbon.

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Earth Catastrophes and Their Impact on the Carbon Cycle

Carbon is one of the most important elements on Earth. It is the basis of life, it is stored and mobilized throughout the Earth from core to crust and it is the basis of the energy sources that are vital to human civilization. This issue will focus on the origins of carbon on Earth, the roles played by large-scale catastrophic carbon perturbations in mass extinctions, the movement and distribution of carbon in large igneous provinces, and the role carbon plays in icehouse–greenhouse climate transitions in deep time. Present-day carbon fluxes on Earth are changing rapidly, and it is of utmost importance that scientists understand Earth’s carbon cycle to secure a sustainable future.

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Diamond Exploration and Resource Evaluation of Kimberlites

Kimberlite rocks and deposits are the eruption products of volatile-rich, silica-poor ultrabasic magmas that originate as small-degree mantle melts at depths in excess of 200 km. Many kimberlites are emplaced as subsurface cylindrical-to-conical pipes and associated sills and dykes. Surficial volcanic deposits of kimberlite are rare. Although kimberlite magmas have distinctive chemical and physical properties, their eruption styles, intensities and durations are similar to conventional volcanoes. Rates of magma ascent and transport through the cratonic lithosphere are informed by mantle cargo entrained by kimberlite, by the geometries of kimberlite dykes exposed in diamond mines, and by laboratory-based studies of dyke mechanics. Outstanding questions concern the mechanisms that trigger and control the rates of kimberlite magmatism.

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Kimberlite Volcanology: Transport, Ascent, and Eruption

Kimberlite rocks and deposits are the eruption products of volatile-rich, silica-poor ultrabasic magmas that originate as small-degree mantle melts at depths in excess of 200 km. Many kimberlites are emplaced as subsurface cylindrical-to-conical pipes and associated sills and dykes. Surficial volcanic deposits of kimberlite are rare. Although kimberlite magmas have distinctive chemical and physical properties, their eruption styles, intensities and durations are similar to conventional volcanoes. Rates of magma ascent and transport through the cratonic lithosphere are informed by mantle cargo entrained by kimberlite, by the geometries of kimberlite dykes exposed in diamond mines, and by laboratory-based studies of dyke mechanics. Outstanding questions concern the mechanisms that trigger and control the rates of kimberlite magmatism.

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Dating Kimberlites: Methods and Emplacement Patterns Through Time

Key to deciphering the origin and tectonic setting of kimberlite magmatism is an accurate understanding of when they formed. Although determining absolute emplacement ages for kimberlites is challenging, recent methodological advances have contributed to a current database of >1,000 precisely dated kimberlite occurrences. Several profound findings emerge from kimberlite geochronology: kimberlites were absent in the first half of Earth history; most kimberlites were emplaced during the Mesozoic; kimberlite magma formation may be triggered by a variety of Earth processes (deep mantle plumes, subduction of oceanic lithosphere, continental rifting); and enhanced periods of kimberlite magmatism coincide with supercontinent breakup.

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Kimberlites from Source to Surface: Insights from Experiments

High-pressure experiments are unconvincing in explaining kimberlites as direct melts of carbonated peridotite because the appropriate minerals do not coexist stably at the kimberlite liquidus. High-pressure melts of peridotite with CO2 and H2O have compositions similar to kimberlites only at pressures where conditions are insufficiently oxidizing to stabilize CO2: they do not replicate the high K2O/Na2O of kimberlites. Kimberlite melts may begin their ascent at ≈300 km depth in reduced conditions as melts rich in MgO and SiO2 and poor in Na2O. These melts interact with modified, oxidized zones at the base of cratons where they gain CO2, CaO, H2O, and K2O and lose SiO2. Decreasing CO2 solubility at low pressures facilitates the incorporation of xenocrystic olivine, resulting in kimberlites’ characteristically high MgO/CaO.

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Kimberlites as Geochemical Probes of Earth’s Mantle

Kimberlites are ultrabasic, Si-undersaturated, low Al, low Na rocks rich in CO2 and H2O. The distinctive geochemical character of kimberlite is strongly influenced by the nature of the local underlying lithospheric mantle. Despite this, incompatible trace element ratios and radiogenic isotope characteristics of kimberlites, filtered for the effects of crustal contamination and alteration, closely resemble rocks derived from the deeper, more primitive, convecting mantle. This suggests that the ultimate magma source is sub-lithospheric. Although the composition of primitive kimberlite melt remains unresolved, kimberlites are likely derived from the convecting mantle, with possible source regions ranging from just below the lithosphere, through the transition zone, to the core–mantle boundary.

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