Thematic Articles

Superhydrous Arc Magmas in the Alpine Context

Magmatic rocks in the Alps are scarce. What little arc magmatism there was pre-dates the Eurasia–Adria collision at 43–34 Ma but ends at 30–29 Ma. Conversely, geochemical data for magmatic rocks from the Alps resemble that of subduction-related magmatic arcs. A characteristic of Alpine magmatism is the occurrence of relatively deep (80–100 km) superhydrous (>8 wt% H2O) low-K primary magmas in the east and shoshonitic K-rich magmas in the west. These features are likely related to the absence of vigorous mantle wedge convection. Superhydrous primary magmas undergo extensive crystallization and fluid saturation at depth, producing high ratios of plutonic to volcanic rocks. We speculate that superhydrous primary arc magmas are a consequence of slow convergence and the initial architecture of subducting crust.

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Formation of the Alpine Orogen by Amagmatic Convergence and Assembly of Previously Rifted Lithosphere

The tectonic and magmatic characteristics of the Alps and Pyrenees during convergence are quite distinct from characteristics associated with classic Benioff-type oceanic subduction. From the initiation of subduction at passive margins until the onset of continental collision, the closure of the Western Tethys never produced a long-lived magmatic arc. This is a consequence of the 3-D architecture of the Western Tethys (a series of hyper-thinned basins and continental blocks) and its narrow width (<500–700 km) prior to convergence. Subduction primarily involved the slow and amagmatic subduction of a narrow domain of dry lithospheric mantle. This type of congested Ampferer subduction led to the sequential and coherent accretion of inherited rifted domains which today form the Alpine and Pyrenean orogens.

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The Heterogeneous Tethyan Oceanic Lithosphere of the Alpine Ophiolites

The Alpine–Apennine ophiolites are lithospheric remnants of the Jurassic Alpine Tethys Ocean. They predominantly consist of exhumed mantle peridotites with lesser gabbroic and basaltic crust and are locally associated with continental crustal material, indicating formation in an environment transitional from an ultra-slow-spreading seafloor to a hyperextended passive margin. These ophiolites represent a unique window into mantle dynamics and crustal accretion in an ultra-slow-spreading extensional environment. Old, pre-Alpine, lithosphere is locally preserved within the mantle sequences: these have been largely modified by reaction with migrating asthenospheric melts. These reactions were active in both the mantle and the crust and have played a key role in creating the heterogeneous oceanic lithosphere in this branch of the Mesozoic Western Tethys.

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Under Pressure: High-Pressure Metamorphism in the Alps

The mechanisms attending the burial of crustal material and its exhumation before and during the Alpine orogeny are controversial. New mechanical models propose local pressure perturbations deviating from lithostatic pressure as a possible mechanism for creating (ultra-)high-pressure rocks in the Alps. These models challenge the assumption that metamorphic pressure can be used as a measure of depth, in this case implying deep subduction of metamorphic rocks beneath the Alpine orogen. We summarize petrological, geochronological and structural data to assess two fundamentally distinct mechanisms of forming (ultra-)high-pressure rocks: deep subduction; or anomalous, non-lithostatic pressure variation. Furthermore, we explore mineral-inclusion barometry to assess the relationship between pressure and depth in metamorphic rocks.

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Ocean Subduction Dynamics in the Alps

The Alps preserve abundant oceanic blueschists and eclogites that exemplify the selective preservation of fragments of relatively short-lived, small, slow-spreading North Atlantic–type ocean basins whose subducting slabs reach down to the Mantle Transition Zone at most. Whereas no subducted fragments were returned during the first half of the subduction history, those exhumed afterwards experienced conditions typical of mature subduction zones worldwide. Sedimentary-dominated units were underplated intermittently, mostly at ~30–40 km depth. Some mafic–ultramafic-dominated units formed close to the continent were subducted to ~80 km and offscraped from the slab only a few million years before continental subduction. Spatiotemporal contrasts in burial and preservation of the fragments reveal how along-strike segmentation of the continental margin affects ocean subduction dynamics.

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Attraction in the Dark: The Magnetism of Speleothems

No matter how quiet and pristine a cave setting may appear, all speleothems contain assemblages of magnetic minerals. These iron oxide minerals are derived largely from overlying soils, though minor fractions may come from the residuum of dissolved bedrock, reworked sediment carried by episodic floods, geomicrobiological activity, and even windblown dust. Regardless of their origin, these minerals become aligned with Earth’s ambient magnetic field before they are fixed within a speleothem’s growing carbonate matrix. Here, we describe how the magnetism of stalagmites and flowstone can be used to chronicle high-resolution geomagnetic behavior and environmental change.

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Cave Decorating with Microbes: Geomicrobiology of Caves

Microorganisms are important for the formation and biogeochemistry of caves. Some caves are energy-rich systems with abundant organic or inorganic chemical energy inputs that support robust microbial ecosystems, but most are extremely oligotrophic settings with slow-growing microbial communities that rely on limited energy resources. Microorganisms are catalysts for element cycling in subterranean environments and act as agents of mineral precipitation and dissolution. Microbes can contribute to cave formation by producing acids and corroding limestone bedrock, and they can form secondary mineral deposits by catalyzing metal oxidation and inducing carbonate precipitation. We describe the energy sources for microbial life in caves, and we review three situations in which microorganisms may play a direct role in mineral deposition and bedrock corrosion.

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Temperature Reconstructions Using Speleothems

Methods for reconstructing past temperatures from speleothems have only recently been developed. Advances in quantitative temperature proxies for speleothems are now allowing critical knowledge gaps to be filled, given the outstanding age control and wide geographical distribution of the speleothem archive. The methods of reconstructing temperatures from speleothems are diverse: they rely on concepts from geochemistry, biology, and physics, and are based on different aspects of speleothems, including water inclusions, calcite, and organic molecules. Combining the different approaches makes temperature reconstructions more robust, affords further insights into the methodologies, and provides constraints on other climate variables.

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Tales from the Underground: Speleothem Records of Past Hydroclimate

Geochemical records from speleothems have significantly advanced our understanding of natural climate variability over the last ~600,000 years. Speleothems are sensitive recorders of past changes in hydroclimate because they can be precisely dated and contain multiple hydrologically sensitive geochemical proxies. Oxygen isotope records from speleothems tell us about the timing and mechanisms of past changes in precipitation amount, temperature, atmospheric circulation, and/or global monsoon intensity. Variations in speleothem carbon isotope ratios or trace element concentrations reflect changes in local water balance, vegetation, and karst hydrology. Speleothem paleoclimate records represent a window into the past that can provide crucial information for understanding how anthropogenic climate change and natural climate variability will impact future water resources on Earth.

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Uranium–Thorium Dating of Speleothems

Speleothems are important timekeepers of Earth’s climate history. A key advantage of speleothems is that they can be dated using U–Th techniques. Mass spectrometric methods for measuring U and Th isotopes has led to vast improvements in measurement precision and a dramatic reduction in sample size. As a result, the timing of past climate, environment, and Earth system changes can be investigated at exceptional temporal precision. In this review, we summarize the principles and history of U–Th dating of speleothems. Finally, we highlight three studies that use U–Th dated speleothems to investigate past changes to the Asian monsoon, constrain the timing of sociopolitical change in ancient civilizations, and develop a speleothem-based calibration of the 14C timescale.

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