Thematic Articles

Constraining the Climates of Rocky Exoplanets

Numerical climate models originally developed for Earth have been adapted to study exoplanetary climates. This is allowing us to investigate the range of properties that might affect an exoplanet’s climate. The recent discovery, and upcoming characterization, of cosmically close rocky exoplanets opens the door toward understanding the processes that shape planetary climates, maybe also leading to insight into the persistent habitability of Earth itself. We summarize the recent advances made in understanding the climate of rocky exoplanets, including their atmospheric structure, chemistry, evolution, and atmospheric and oceanic circulation. We describe current and upcoming astronomical observations that will constrain the climate of rocky exoplanets and describe how modeling tools will both inform and interpret future observations.

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The Diversity of Exoplanets: From Interior Dynamics to Surface Expressions

The coupled interior–atmosphere system of terrestrial exoplanets remains poorly understood. Exoplanets show a wide variety of sizes, densities, surface temperatures, and interior structures, with important knock-on effects for this coupled system. Many exoplanets are predicted to have a “stagnant lid” at the surface, with a rigid stationary crust, sluggish mantle convection, and only minor volcanism. However, if exoplanets have Earth-like plate tectonics, which involves several discrete, slowly moving plates and vigorous tectono-magmatic activity, then this may be critical for planetary habitability and have implications for the development (and evolution) of life in the galaxy. Here, we summarize our current knowledge of coupled planetary dynamics in the context of exoplanet diversity.

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Exogeology from Polluted White Dwarfs

It is difficult to study the interiors of terrestrial planets in the Solar System and the problem is magnified for distant exoplanets. However, sometimes nature is helpful. Some planetary bodies are torn to fragments and consumed by the strong gravity close to the descendants of Sun-like stars, white dwarfs. We can deduce the general composition of the planet when we observe the spectroscopic signature of the white dwarf. Most planetary fragments that fall into white dwarfs appear to be rocky with a variable fraction of associated ice and carbon. These white dwarf planetary systems provide a unique opportunity to study the geology of exoplanetary systems.

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Compositional Diversity of Rocky Exoplanets

To test whether exoplanets are similar to Earth, knowledge of their host star composition is essential. Stellar elemental abundances and planetary orbital data show that of the ~5,000 known minerals, exoplanetary silicate mantles contain mostly olivine, orthopyroxene, and clinopyroxene, ± quartz and magnesiowüstite at the extremes, while wholly exotic mineralogies are unlikely. Understanding the geology of exoplanets requires a better marriage of geological insights to astronomical data. The study of exoplanets is like a mirror: it reflects our incomplete understanding of Earth and neighboring planets. New geological/planetary experiments, informed by exoplanet studies, are needed for effective progress.

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Why Geosciences and Exoplanetary Sciences Need Each Other

The study of planets outside our Solar System may lead to major advances in our understanding of the Earth and may provide insight into the universal set of rules by which planets form and evolve. To achieve these goals requires applying geoscience’s wealth of Earth observations to fill in the blanks left by the necessarily minimal exoplanetary observations. In turn, many of Earth’s one-offs—plate tectonics, surface liquid water, a large moon, and life; long considered as “Which came first?” conundrums for geoscientists—may find resolution in the study of exoplanets that possess only a subset of these phenomena.

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Carbonatites and Global Tectonics

Carbonatites have formed for at least the past three billion years. But over the past 700 My the incidence of carbonatites have significantly increased. We compile an updated list of 609 carbonatite occurrences and plot 387 of known age on plate tectonic reconstructions. Plate reconstructions from Devonian to present show that 75% of carbonatites are emplaced within 600 km of craton edges. Carbonatites are also associated with large igneous provinces, orogenies, and rift zones, suggesting that carbonatite magmatism is restricted to discrete geotectonic environments that can overlap in space and time. Temporal constraints indicate carbonatites and related magmas may form an ephemeral but significant flux of carbon between the mantle and atmosphere.

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The Distinctive Mineralogy of Carbonatites

The mineralogy of carbonatites reflects both the diversity of the sources of their parent magmas and their unusual chemistry. Carbonatites contain diverse suites of both primary magmatic minerals and later hydrothermal products. We present a summary of the variety of minerals found in carbonatites, and note the economic importance of some of them, particularly those that are major sources of “critical elements”, such as Nb and rare earth elements (REEs), which are essential for modern technological applications. Selected mineral groups are then discussed in detail: the REE carbonates, the alkali-rich ephemeral minerals that are rarely preserved but that may be important in the petrogenesis of carbonatites and their metasomatic haloes in adjacent rocks, and the Nb-rich oxides of the pyrochlore supergroup.

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Formation of Rare Earth Deposits in Carbonatites

Carbonatites and related rocks are the premier source for light rare earth element (LREE) deposits. Here, we outline an ore formation model for LREE-mineralised carbonatites, reconciling field and petrological observations with recent experimental and isotopic advances. The LREEs can strongly partition to carbonatite melts, which are either directly mantle-derived or immiscible from silicate melts. As carbonatite melts evolve, alkalis and LREEs concentrate in the residual melt due to their incompatibility in early crystallising minerals. In most carbonatites, additional fractionation of calcite or ferroan dolomite leads to evolution of the residual liquid into a mobile alkaline “brine-melt” from which primary alkali REE carbonates can form. These primary carbonates are rarely preserved owing to dissolution by later fluids, and are replaced in-situ by monazite and alkali-free REE-(fluor)carbonates.

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Carbonatitic Melts and Their Role in Diamond Formation in the Deep Earth

Carbonatitic high-density fluids and carbonate mineral inclusions in ­lithospheric and sub-lithospheric diamonds reveal comparable compositions to crustal carbonatites and, thus, support the presence of carbonatitic melts to depths of at least the mantle transition zone (~410–660 km depth). Diamonds and high pressure–high temperature (HP–HT) experiments confirm the stability of lower mantle carbonates. Experiments also show that carbonate melts have extremely low viscosity in the upper mantle. Hence, carbonatitic melts may participate in the deep (mantle) carbon cycle and be highly effective metasomatic agents. Deep carbon in the upper mantle can be mobilized by metasomatic carbonatitic melts, which may have become increasingly volumetrically significant since the onset of carbonate subduction (~3 Ga) to the present day.

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Evolution of Carbonatite Magmas in the Upper Mantle and Crust

Carbonatites are the most silica-poor magmas known and are amongst Earth’s most enigmatic igneous rocks. They crystallise to rocks dominated by the carbonate minerals calcite and dolomite. We review models for carbonatite petrogenesis, including direct partial melting of mantle lithologies, exsolution from silica-undersaturated alkali silicate melts, or direct fractionation of carbonated silicate melts to carbonate-rich residual melts. We also briefly discuss carbonatite–mantle wall-rock reactions and other processes at mid- to upper crustal depths, including fenitisation, overprinting by carbohydrothermal fluids, and reaction between carbonatite melt and crustal lithologies.

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